The board has two MOSFET outputs, io.4-MOS-GND and io.5-MOS-GND. The test YAML maps GPIO.4 to mist coolant (M7) and GPIO.5 to flood coolant (M8); M9 turns both off. You'll confirm each terminal switches between 0 V and about 24 V with a multimeter while its indicator LED follows along. This is the first step that uses the multimeter — take it slowly.
io.4-MOS-GND tells you it is the GND side that output io.4 switches. In normal use your load wires between Vmot-Main (+) and io.X-MOS-GND; turning the output ON connects io.X-MOS-GND to GND, so the full motor voltage (Vmot, ~24 V) appears across the load. With no load attached, the multimeter reads that voltage straight across the two terminal pins — about 0 V when off, ~24 V when on.
Set the multimeter to DC voltage, auto-range. On the orange io.4-MOS-GND terminal, put the probes across its two pins — top pin and bottom pin, exactly as in the photo:
With nothing switched on it reads about 0 V. (If the meter shows a minus sign, your probes are reversed — just swap them.)
io.4-MOS-GND terminalio.5-MOS-GND terminalM7, io.5 reads about 24 V with M8, and each returns to about 0 V after M9. If both do, the MOSFET outputs are good.